Journal article
A concise approach to the synthesis of all twelve 5-deoxyhexoses: D-tagatose-3-epimerase-a reagent that is both specific and general
- Abstract:
-
2-Deoxy-d-glucitol and 2-deoxy-d-allitol, both prepared as crystalline polyols from d-erythronolactone, are oxidized by Gluconobacter thailandicus NBRC 3254 to 5-deoxy-d-threo-hexulose [5-deoxy-d-fructose = 5-deoxy-l-sorbose] and 5-deoxy-d-erythro-hexulose [5-deoxy-l-psicose = 5-deoxy-d-tagatose], respectively. d-Tagatose-3-epimerase (DTE) equilibrates 5-deoxy-d-fructose to 5-deoxy-d-psicose and 5-deoxy-l-psicose to 5-deoxy-l-fructose, providing substrates for the preparation of all eight d- ...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- TETRAHEDRON LETTERS More from this journal
- Volume:
- 50
- Issue:
- 26
- Pages:
- 3559-3563
- Publication date:
- 2009-07-01
- DOI:
- ISSN:
-
0040-4039
Item Description
- Language:
-
English
- Pubs id:
-
pubs:41241
- UUID:
-
uuid:ea44fb52-ba64-4154-a524-002f9be1f87b
- Local pid:
-
pubs:41241
- Source identifiers:
-
41241
- Deposit date:
-
2012-12-19
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- Copyright date:
- 2009
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