Journal article

Novel primary phosphinecarboxamides derived from diamines

Abstract:: We describe the synthesis of N-functionalised phosphinecarboxamides obtained by reaction of the 2-phosphaethynolate anion (PCO−) with diamines, specifically hydrazine, methylenediamine and ethylenediamine, in the presence of acid. The resulting neutral compounds can be deprotonated to generate phosphide anions that, when further reacted with electrophiles, form secondary phosphines

Publication status:: Published

Peer review status:: Peer reviewed

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APA Style

Faria, E. N., Jupp, A. R., & Goicoechea, J. M. (2021). Novel primary phosphinecarboxamides derived from diamines. Dalton Transactions, 50(20), 6991–6996.

MLA Style

Faria, EN, et al. “Novel Primary Phosphinecarboxamides Derived from Diamines.” Dalton Transactions, vol. 50, no. 20, 2021, pp. 6991–96.

Chicago Style

Faria, EN, AR Jupp, and JM Goicoechea. 2021. “Novel Primary Phosphinecarboxamides Derived from Diamines.” Dalton Transactions 50 (20): 6991–96.
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Files:: Faria_et_al_2021_Novel_primary_phosphinecarboxamides.pdf

(Preview, Version of record, pdf, 917.9KB, Terms of use)

Publisher copy:: 10.1039/d1dt01198g

Publication website:: https://pure-oai.bham.ac.uk/ws/files/132588805/d1dt01198g.pdf

Authors

+ Faria, EN More by this author

Institution:: University of Oxford
Role:: Author

+ Jupp, AR More by this author

Institution:: University of Oxford
Role:: Author
ORCID:: 0000-0003-4360-5838

+ Goicoechea, JM More by this author

Institution:: University of Oxford
Role:: Author
ORCID:: 0000-0002-7311-1663

+ Conselho Nacional de Desenvolvimento Científico e Tecnológico More from this funder

Funder identifier:: 10.13039/501100003593
Grant:: 233778/2014-4

+ Engineering and Physical Sciences Research Council More from this funder

Funder identifier:: 10.13039/501100000266

Publisher:: Royal Society of Chemistry
Journal:: Dalton Transactions More from this journal
Volume:: 50
Issue:: 20
Pages:: 6991-6996
Publication date:: 2021-05-25
DOI:: 10.1039/d1dt01198g
EISSN:: 1477-9234
ISSN:: 1477-9226

Language:: English
Keywords:: Chemistry

Primary (astronomy)

Physics
Pubs id:: 1174487
Local pid:: pubs:1174487
Source identifiers:: W3157429221
Deposit date:: 2026-03-24
ARK identifier:: ark:/29072/ora_e9d1a2f60d2846b7900d3b68d597658d

Terms of use

Copyright date:: 2021

Licence:: CC Attribution-NonCommercial (CC BY-NC)

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