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In situ electrochemical ESR and voltammetric studies on the anodic oxidation of para-haloanilines in acetonitrile.

Abstract:

An in situ electrochemical electron spin resonance (ESR) study on the electro-oxidation of para-chloroaniline, para-bromoaniline, and para-iodoaniline dissolved in acetonitrile at gold electrodes is reported. ESR spectra obtained using a tubular flow cell reveal the presence of a paramagnetic dimer product derived from para-aminodiphenylamine, during oxidative electrolysis, suggesting the coupling of reactive electrogenerated radical cations with neutral parent haloaniline molecules. The ESR ...

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Publication status:
Published

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Publisher copy:
10.1021/jp058064p

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
journal of physical chemistry. B More from this journal
Volume:
109
Issue:
25
Pages:
12636-12649
Publication date:
2005-06-01
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
Pubs id:
pubs:33553
UUID:
uuid:e9cab9f7-2fe6-46ab-9345-38d1b736a135
Local pid:
pubs:33553
Source identifiers:
33553
Deposit date:
2012-12-19

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