Journal article
In situ electrochemical ESR and voltammetric studies on the anodic oxidation of para-haloanilines in acetonitrile.
- Abstract:
-
An in situ electrochemical electron spin resonance (ESR) study on the electro-oxidation of para-chloroaniline, para-bromoaniline, and para-iodoaniline dissolved in acetonitrile at gold electrodes is reported. ESR spectra obtained using a tubular flow cell reveal the presence of a paramagnetic dimer product derived from para-aminodiphenylamine, during oxidative electrolysis, suggesting the coupling of reactive electrogenerated radical cations with neutral parent haloaniline molecules. The ESR ...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- journal of physical chemistry. B More from this journal
- Volume:
- 109
- Issue:
- 25
- Pages:
- 12636-12649
- Publication date:
- 2005-06-01
- DOI:
- EISSN:
-
1520-5207
- ISSN:
-
1520-6106
Item Description
- Language:
-
English
- Pubs id:
-
pubs:33553
- UUID:
-
uuid:e9cab9f7-2fe6-46ab-9345-38d1b736a135
- Local pid:
-
pubs:33553
- Source identifiers:
-
33553
- Deposit date:
-
2012-12-19
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- Copyright date:
- 2005
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