Journal article

Li0.7NbS2: structural effects of increased alkali metal content

Abstract:: Crystals of lithium niobium disulfide [LiyNbS2; y = 0.70 (9)] have been prepared by separated reactants metathesis (SRM) at 1073 K. Single-crystal data collected at reduced temperature [150 (2) K] indicate that the compound is isostructural with Li0.63NbS2 [Salyer, Barker, Blake, Gregory and Wilson (2003). Acta Cryst. C59, i4-i6], crystallizing in the hexagonal space group P63/mmc (No. 194). Li 0.7NbS2 shows an expansion of both the a and c lattice parameters when compared with previously reported results on Li yNbS2 intercalation compounds with y < 0.70. This provides the first single-crystal structural evidence of unit cell expansion with increasing lithium content in LiyNbS2, where y > 0.5. κ 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

Publication status:: Published

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APA Style

Salyer, P., Barker, M. G., Gregory, D., Jones, M., & Wilson, C. (2003). Li0.7NbS2: structural effects of increased alkali metal content. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 59(8), I112–I115.

MLA Style

Salyer, P, et al. “Li0.7NbS2: Structural Effects of Increased Alkali Metal Content.” ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol. 59, no. 8, 2003, pp. I112–I115.

Chicago Style

Salyer, P, MG Barker, D Gregory, M Jones, and C Wilson. 2003. “Li0.7NbS2: Structural Effects of Increased Alkali Metal Content.” ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 59 (8): I112–I115.
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Publisher copy:: 10.1107/S1600536803014855

Authors

+ Salyer, P More by this author

Role:: Author

+ Barker, MG More by this author

Role:: Author

+ Gregory, D More by this author

Role:: Author

+ Jones, M More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Wilson, C More by this author

Role:: Author

Journal:: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE More from this journal
Volume:: 59
Issue:: 8
Pages:: I112-I115
Publication date:: 2003-08-01
DOI:: 10.1107/S1600536803014855
EISSN:: 1600-5368
ISSN:: 1600-5368

Language:: English
Pubs id:: pubs:104479
UUID:: uuid:e9b52855-eb6a-498c-8306-4c957437cd6f
Local pid:: pubs:104479
Source identifiers:: 104479
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_e9b52855eb6a498c83064c957437cd6f

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Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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