Journal article

New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible.

Abstract:: Cyclic voltammetry carried out at a wide range of supporting electrolyte concentrations and compositions can elucidate additional kinetic and mechanistic details of the electrochemical reduction of aryl halides. The cleavage of the C-Br bond is reversible, driven by H abstraction and the second electron transfer. This is a new chemical insight, as the cleavage of such bonds has usually been regarded as irreversible.

Publication status:: Published

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APA Style

Wang, Y., Barnes, E., & Compton, R. (2012). New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible. Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry, 13(15), 3441–3444.

MLA Style

Wang, Y, et al. “New Chemical Insights Using Weakly Supported Voltammetry: the Reductive Cleavage of Aryl-Br Bonds Is Reversible.” Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry, vol. 13, no. 15, 2012, pp. 3441–44.

Chicago Style

Wang, Y, E Barnes, and R Compton. 2012. “New Chemical Insights Using Weakly Supported Voltammetry: the Reductive Cleavage of Aryl-Br Bonds Is Reversible.” Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry 13 (15): 3441–44.
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Publisher copy:: 10.1002/cphc.201200480

Authors

+ Wang, Y More by this author

Role:: Author

+ Barnes, E More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: Chemphyschem : a European journal of chemical physics and physical chemistry More from this journal
Volume:: 13
Issue:: 15
Pages:: 3441-3444
Publication date:: 2012-10-01
DOI:: 10.1002/cphc.201200480
EISSN:: 1439-7641
ISSN:: 1439-4235

Language:: English
Keywords:: reaction mechanisms

kinetics

redox chemistry

cyclic voltammetry

electrochemistry
Pubs id:: pubs:345608
UUID:: uuid:e9aaf554-5fc8-4d23-8e7c-37114ce73b66
Local pid:: pubs:345608
Source identifiers:: 345608
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_e9aaf5545fc84d238e7c37114ce73b66

Terms of use

Copyright date:: 2012

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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