- Abstract:
-
Polycrystalline samples of Ln(18)Li(8)Rh(5-x)Fe(x)O(39) (Ln = La, Nd; 0.5 < or = x < or = 5) have been synthesized by a solid-state method and studied by a combination of dc and ac magnetometry, neutron diffraction, and Mossbauer spectroscopy. All compositions adopt a cubic structure (space group Pm3n, a(0) approximately 12 A) based on intersecting 111 chains made up of alternating octahedral and trigonal-prismatic coordination sites. These chains occupy channels within a Ln-O framework...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic100377s
-
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- Journal:
- Inorganic chemistry
- Volume:
- 49
- Issue:
- 13
- Pages:
- 5912-5922
- Publication date:
- 2010-07-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:e96394fa-8977-48a9-924f-a61d27b9c2c7
- Source identifiers:
-
60444
- Local pid:
- pubs:60444
- Language:
- English
- Copyright date:
- 2010
Journal article
Structural chemistry and magnetic properties of Ln18Li8Rh(5-x)Fe(x)O39 (Ln = La, Nd).
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