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Structural chemistry and magnetic properties of Ln18Li8Rh(5-x)Fe(x)O39 (Ln = La, Nd).

Abstract:

Polycrystalline samples of Ln(18)Li(8)Rh(5-x)Fe(x)O(39) (Ln = La, Nd; 0.5 < or = x < or = 5) have been synthesized by a solid-state method and studied by a combination of dc and ac magnetometry, neutron diffraction, and Mossbauer spectroscopy. All compositions adopt a cubic structure (space group Pm3n, a(0) approximately 12 A) based on intersecting 111 chains made up of alternating octahedral and trigonal-prismatic coordination sites. These chains occupy channels within a Ln-O framework...

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Publication status:
Published

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Publisher copy:
10.1021/ic100377s

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Dutton, SE More by this author
Thammajak, N More by this author
Grandjean, F More by this author
Sougrati, MT More by this author
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Journal:
Inorganic chemistry
Volume:
49
Issue:
13
Pages:
5912-5922
Publication date:
2010-07-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:e96394fa-8977-48a9-924f-a61d27b9c2c7
Source identifiers:
60444
Local pid:
pubs:60444
Language:
English

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