Journal article

Transition-metal-mediated activation of the heptaarsenide trianion: isolation of a diaryltetraarsenabutadienediide.

Abstract:: Reaction of an ethylenediamine solution of K(3)As(7) with the low-valent, low-coordinate cobalt(II) complex [Co(mes)(2)(PEt(2)Ph)(2)] yielded the novel dianionic species [Co(η(3)-As(3)){η(4)-As(4)(mes)(2)}](2-) (1). The [η(4)-As(4)(mes)(2)](2-) moiety present in 1 is a rare example of a group 15 analogue of a butadienediide.

Publication status:: Published

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APA Style

Knapp, C., Westcott, B., Raybould, M., McGrady, J., & Goicoechea, J. (2012). Transition-metal-mediated activation of the heptaarsenide trianion: isolation of a diaryltetraarsenabutadienediide. Chemical Communications, 48(100), 12183–12185.

MLA Style

Knapp, C., et al. “Transition-Metal-Mediated Activation of the Heptaarsenide Trianion: Isolation of a Diaryltetraarsenabutadienediide.” Chemical Communications, vol. 48, no. 100, 2012, pp. 12183–85.

Chicago Style

Knapp, C, B Westcott, M Raybould, J McGrady, and J Goicoechea. 2012. “Transition-Metal-Mediated Activation of the Heptaarsenide Trianion: Isolation of a Diaryltetraarsenabutadienediide.” Chemical Communications 48 (100): 12183–85.
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Publisher copy:: 10.1039/c2cc36888a

Authors

+ Knapp, C More by this author

Role:: Author

+ Westcott, B More by this author

Role:: Author

+ Raybould, M More by this author

Role:: Author

+ McGrady, J More by this author

Role:: Author

+ Goicoechea, J More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Chemical Communications More from this journal
Volume:: 48
Issue:: 100
Pages:: 12183-12185
Publication date:: 2012-12-01
DOI:: 10.1039/c2cc36888a
EISSN:: 1364-548X
ISSN:: 1359-7345

Language:: English
Pubs id:: pubs:363799
UUID:: uuid:e9600a65-64a3-4801-adbc-a046f5009da3
Local pid:: pubs:363799
Source identifiers:: 363799
Deposit date:: 2013-11-17

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Copyright date:: 2012

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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