Journal article

VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM

Abstract:: Voltammetric studies at a channel electrode irradiated with monochromatic visible light have been carried out to demonstrate that the photolysis of fac-Mo(CO)3{η3-[(Ph2PCH2CH 2)2PPh]}† in acetonitrile or dimethylformamide solution leads to the formation of the corresponding mer-isomer. No photofragmentation resulting in the loss of carbon monoxide or phosphine is observed on the voltammetric timescale. Kinetic parameters for the photo-isomerisation are reported.

Publication status:: Published

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APA Style

Compton, R., Eklund, J., Hallik, A., Kumbhat, S., Bond, A., & Colton, R. (1995). VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 7, 1327–1331.

MLA Style

Compton, R, et al. “VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM.” JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, no. 7, 1995, pp. 1327–31.

Chicago Style

Compton, R, J Eklund, A Hallik, S Kumbhat, A Bond, and R Colton. 1995. “VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM.” JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, no. 7: 1327–31.
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Publisher copy:: 10.1039/p29950001327

Authors

+ Compton, R More by this author

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+ Eklund, J More by this author

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+ Hallik, A More by this author

Role:: Author

+ Kumbhat, S More by this author

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+ Bond, A More by this author

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Journal:: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 More from this journal
Issue:: 7
Pages:: 1327-1331
Publication date:: 1995-07-01
DOI:: 10.1039/p29950001327
EISSN:: 1364-5471
ISSN:: 0300-9580

Language:: English
Pubs id:: pubs:44852
UUID:: uuid:e94ef838-2ab0-4a76-8201-69c69dfc78fb
Local pid:: pubs:44852
Source identifiers:: 44852
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_e94ef8382ab04a76820169c69dfc78fb

Terms of use

Copyright date:: 1995

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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