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Hole-mediated photoredox catalysis: tris( <i>p</i> -substituted)biarylaminium radical cations as tunable, precomplexing and potent photooxidants

Abstract:
Triarylamines are demonstrated as novel, tunable electroactivated photocatalysts that use dispersion precomplexation to harness the full potential of the visible photon (>4.0 V vs. SCE) in anti-Kasha photo(electro)chemical super-oxidations of arenes.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/d0qo01609h

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Role:
Author
ORCID:
0000-0002-3508-8415
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Role:
Author
ORCID:
0000-0003-2747-2326
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Role:
Author
ORCID:
0000-0001-6131-6787
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Role:
Author
ORCID:
0000-0002-3140-5399
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Role:
Author
ORCID:
0000-0002-4344-8118


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Funder identifier:
10.13039/501100001823
Grant:
LM2018140
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Funder identifier:
10.13039/100005156


Publisher:
Royal Society of Chemistry (RSC)
Journal:
Organic Chemistry Frontiers More from this journal
Volume:
8
Issue:
6
Pages:
1132-1142
Publication date:
2021-03-23
DOI:
ISSN:
2052-4110


Language:
English
Keywords:
Pubs id:
1199935
Local pid:
pubs:1199935
Source identifiers:
W3135296881
Deposit date:
2026-03-26
ARK identifier:
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