Journal article icon

Journal article

Single entity electrocatalysis: oxygen reduction mediated via methyl viologen doped Nafion nanoparticles

Abstract:

Nafion particles doped with methyl viologen are shown to be electrocatalytic towards oxygen reduction in aqueous solution when immobilised on a carbon electrode surface, with the formation of hydrogen peroxide. In this way an efficient homogeneous electron transfer mediator, methyl viologen, can be confined to act heterogeneously with the benefits of that type of process without losing effectiveness. Kinetic and mechanistic parameters are deduced from cyclic voltammetry and from single entity...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

Actions


Access Document


Files:
Publisher copy:
10.1039/C8CP02311E

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Oxford college:
St Cross College
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Physical Chemistry Chemical Physics Journal website
Volume:
20
Issue:
23
Pages:
15795-15806
Publication date:
2018-05-23
Acceptance date:
2018-05-23
DOI:
ISSN:
1463-9076
Pubs id:
pubs:853612
URN:
uri:e92b33cb-5e6b-4b52-8894-4e8929afed2a
UUID:
uuid:e92b33cb-5e6b-4b52-8894-4e8929afed2a
Local pid:
pubs:853612

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP