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Journal article

Time-resolved CIDNP and laser flash photolysis study of the photoreactions of N-acetyl histidine with 2,2 '-dipyridyl in aqueous solution

Abstract:

The reaction mechanism and details of the formation of CIDNP (chemically induced dynamic nuclear polarization) in the photoreactions of 2,2′-dipyridyl (DP) and N-acetyl histidine (HisH) in aqueous solution have been studied using laser flash photolysis and time-resolved CIDNP techniques. The triplet state TDP reacts with protonated HisH 2+ via hydrogen atom transfer with a rate constant k H = 1.2 × 10 ...

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Publication status:
Published

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Publisher copy:
10.1021/jp000019o

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY A More from this journal
Volume:
104
Issue:
30
Pages:
6912-6916
Publication date:
2000-08-03
DOI:
EISSN:
1520-5215
ISSN:
1089-5639
Language:
English
Pubs id:
pubs:37538
UUID:
uuid:e91c0dc2-4ca8-41d2-b31b-62cfe33067ac
Local pid:
pubs:37538
Source identifiers:
37538
Deposit date:
2012-12-19

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