Journal article icon

Journal article

Structure of the Chromium(III) salt [Cp-2*Cr](+)[Cp*CrCl3](-)

Abstract:

© 1998 International Union of Crystallography The title compound, bis(η5-pentamethylcyclopentadienyl) chromium (III) trichloro (η5-pentamethylcyclopentadienyl)chromium(III), [Cr(C10H15)2][CrCl3(C 10-H15)], is a salt consisting of discrete anionic [{η5-C5(CH3)5}CrCl 3]- and cationic [{η5-C5(CH3)5} 2Cr]+ chromium(III) species. The anion adopts a 'three-legged piano-stool' structure, whereas the cation displays a staggered orientation of the C5 rings and approximates to D5d local symmetry. The C...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1107/S0108270197011256

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Volume:
54
Issue:
1
Pages:
47-49
Publication date:
1998-01-15
DOI:
ISSN:
0108-2701
URN:
uuid:e8e24d74-be65-40c2-a7bb-f46fd45c282c
Source identifiers:
46077
Local pid:
pubs:46077
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP