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Chiral Group 4 Cyclopentadienyl Complexes and Their Use in Polymerization of Lactide Monomers

Abstract:

A family of group 4 alkoxide and aryloxide complexes of a chiral cyclopentadienyl-derived (hydro)permethylpentalenyl ligand (C8Me 6H; Pn*(H)) have been prepared and fully characterized. Both racemic and enantiopure complexes of all group 4 congeners were prepared with a wide variety of alkoxide and aryloxide ligands. The complexes Pn*(H)Ti(OtBu)3 (1), Pn*(H)Ti(O-2,6-Me-C 6H3)3 (2), Pn*(H)Zr(OtBu) 3 (3), Pn*(H)Zr(OCH2Ph)3 (4), Pn*(H)Zr(S-OCH{CH3}C6H5)3 (5), Pn*(H)Zr(rac-OCH{CH3}C6H5)3 (6), Pn*...

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Publication status:
Published

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Publisher copy:
10.1021/om500634a

Authors


Turner, ZR More by this author
Buffet, J-C More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Publisher:
American Chemical Society
Journal:
ORGANOMETALLICS
Volume:
33
Issue:
14
Pages:
3891-3903
Publication date:
2014-07-28
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:e8da1838-d760-40f5-87ad-a3487b674249
Source identifiers:
480670
Local pid:
pubs:480670
Language:
English

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