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The long-time chronoamperometric current at an inlaid disk electrode

Abstract:

Existing analytical solutions for the long-time chronoamperometric current response at an inlaid disk electrode are restricted to diffusion-limited currents due to extreme polarisation or reversible kinetics at the electrode surface. In this article, we derive an approximate analytical solution for the long-time-dependent current when the kinetics of the redox reaction at the electrode surface are quasi-reversible and the diffusion coefficients of the oxidant and reductant are different. We a...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Mathematical Institute
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY More from this journal
Volume:
673
Pages:
48-57
Publication date:
2012-05-15
DOI:
ISSN:
1572-6657
Language:
English
Keywords:
Pubs id:
pubs:329406
UUID:
uuid:e8d0c388-6ebc-412a-98bc-c4f3bb2ae90f
Local pid:
pubs:329406
Source identifiers:
329406
Deposit date:
2013-11-16

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