Journal article

Conformational preferences of a polar biaryl: a phase- and enantiomeric purity-dependent molecular hinge.

Abstract:: The favored (R(S)*,M*) diastereoisomer of 2-aryl-pyridine 1 in the solution state results from intramolecular dipole-dipole interactions. In the crystalline state, intermolecular interactions dominate, and the conformation switches reversibly to (R(S)*,P*). Only racemic 1 exhibits this switching property: enantiomerically pure 1 exists as the (R(S)*,M*) diastereoisomer in both the solution and crystalline state.

Publication status:: Published

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APA Style

Clayden, J., Fletcher, S., Rowbottom, S., & Helliwell, M. (2009). Conformational preferences of a polar biaryl: a phase- and enantiomeric purity-dependent molecular hinge. Organic Letters, 11(11), 2313–2316.

MLA Style

Clayden, J, et al. “Conformational Preferences of a Polar Biaryl: a Phase- and Enantiomeric Purity-Dependent Molecular Hinge.” Organic Letters, vol. 11, no. 11, 2009, pp. 2313–16.

Chicago Style

Clayden, J, S Fletcher, S Rowbottom, and M Helliwell. 2009. “Conformational Preferences of a Polar Biaryl: a Phase- and Enantiomeric Purity-Dependent Molecular Hinge.” Organic Letters 11 (11): 2313–16.
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Publisher copy:: 10.1021/ol9006635

Authors

+ Clayden, J More by this author

Role:: Author

+ Fletcher, S More by this author

Role:: Author

+ Rowbottom, S More by this author

Role:: Author

+ Helliwell, M More by this author

Role:: Author

Journal:: Organic letters More from this journal
Volume:: 11
Issue:: 11
Pages:: 2313-2316
Publication date:: 2009-06-01
DOI:: 10.1021/ol9006635
EISSN:: 1523-7052
ISSN:: 1523-7060

Language:: English
Pubs id:: pubs:117865
UUID:: uuid:e8ce147a-171c-4047-a3fc-357acdfc5fa4
Local pid:: pubs:117865
Source identifiers:: 117865
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_e8ce147a171c4047a3fc357acdfc5fa4

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Copyright date:: 2009

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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