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Anion-induced shuttling of a naphthalimide triazolium rotaxane.

Abstract:

The anion-templated synthesis of a rotaxane structure, incorporating the new naphthalimide triazolium motif, is described and the interlocked host shown to exhibit selective, uni-directional, anion-induced shuttling. Initial pseudorotaxane investigations demonstrate the ability of a naphthalimide triazolium threading component to form interpenetrated assemblies with counter-anion-dependent co-conformations. (1)H NMR studies reveal that the shuttling behaviour of the analogous rotaxane host sy...

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Publication status:
Published

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Publisher copy:
10.1002/chem.201200317

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany) More from this journal
Volume:
18
Issue:
23
Pages:
7100-7108
Publication date:
2012-06-01
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Language:
English
Keywords:
Pubs id:
pubs:329003
UUID:
uuid:e8cdc7c8-9109-4e45-a678-01047591ad99
Local pid:
pubs:329003
Source identifiers:
329003
Deposit date:
2012-12-19

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