Journal article

Palladium-catalyzed asymmetric synthesis of 2-alkynyl oxacycles.

Abstract:: Oxyacetylene: Unusual palladium-catalyzed cyclizations of cyclic and acyclic propargylic carbonates give 2-alkynyl oxacycles. The reactions proceed with very high stereoselectivity for both syn- and anti-disubstituted furans and pyrans, and with exceptional regioselectivity. In addition, two-directional cyclizations of bis-propargylic carbonate substrates yield bifurans with complete stereocontrol for all diastereomers. © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

Publication status:: Published

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APA Style

Daniels, D., Thompson, A., & Anderson, E. (2011). Palladium-catalyzed asymmetric synthesis of 2-alkynyl oxacycles. Angewandte Chemie (International Ed. in English), 50(48), 11506–11510.

MLA Style

Daniels, D, et al. “Palladium-Catalyzed Asymmetric Synthesis of 2-Alkynyl Oxacycles.” Angewandte Chemie (International Ed. in English), vol. 50, no. 48, 2011, pp. 11506–10.

Chicago Style

Daniels, D, A Thompson, and E Anderson. 2011. “Palladium-Catalyzed Asymmetric Synthesis of 2-Alkynyl Oxacycles.” Angewandte Chemie (International Ed. in English) 50 (48): 11506–10.
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Publisher copy:: 10.1002/anie.201105720

Authors

+ Daniels, D More by this author

Role:: Author

+ Thompson, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Anderson, E More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 50
Issue:: 48
Pages:: 11506-11510
Publication date:: 2011-11-01
DOI:: 10.1002/anie.201105720
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: Catalysis

Alkynes

Furans

Palladium

Cyclization

Stereoisomerism
Pubs id:: pubs:206032
UUID:: uuid:e8c7460e-d343-402c-ad2d-bcfe147dabd2
Local pid:: pubs:206032
Source identifiers:: 206032
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_e8c7460ed343402cad2dbcfe147dabd2

Terms of use

Copyright date:: 2011

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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