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Cesium- and rubidium-selective redox-active Bis(calix[4]diquinone) ionophores

Abstract:
The length of the bridging alkylene chain between two calix[4]diquinone moieties determines the selectivity of the receptors for Group 1 metal ions. These redox-active receptors exhibit remarkable selectivity preferences and substantial electrochemical recognition effects towards Cs+ and Rb+ ions. The solid-state crystal structure of the Cs+ complex of a bis(calix[4]diquinone) derivative is shown (green: Cs+, red: oxygen).
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION More from this journal
Volume:
40
Issue:
12
Pages:
2265-+
Publication date:
2001-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:37841
UUID:
uuid:e8bf09a9-06b7-4ca5-aa11-a6d066d943f0
Local pid:
pubs:37841
Source identifiers:
37841
Deposit date:
2012-12-19
ARK identifier:

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