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Isomer selective ion-exchange intercalation of nitrophenolates into the layered double hydroxide [LiAl2(OH)(6)]Cl center dot xH(2)O

Abstract:

The anions 4-nitrophenolate (4-NP) and 2,4-dinitrophenolate (2,4-DNP) undergo anion-exchange intercalation with [LiAl2(OH) 6]Cl·xH2O, ([Li-Al-Cl] LDH), to yield the fully exchanged intercalates [LiAl2(OH)6]{4-NP}·2H 2O and [LiAl2(OH)6]{2,4-DNP}·H 2O respectively. 4-NP can be selectively intercalated in [Li-Al-Cl] LDH from an equimolar mixture of 2-nitrophenolate (2-NP), 3-nitrophenolate (3-NP) and 4-nitrophenolate (4-NP). Intercalation of 2,4-DNP is competitive with intercalation of 4-NP into...

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Publication status:
Published

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Publisher copy:
10.1039/b514638k

Authors


Ragavan, A More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
JOURNAL OF MATERIALS CHEMISTRY
Volume:
16
Issue:
6
Pages:
602-608
Publication date:
2006-02-14
DOI:
EISSN:
1364-5501
ISSN:
0959-9428
URN:
uuid:e8884ff1-9598-4a26-a31c-3ad4ae63cd36
Source identifiers:
51305
Local pid:
pubs:51305
Language:
English

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