Journal article
Nitrite-templated synthesis of lanthanide-containing [2]rotaxanes for anion sensing.
- Abstract:
- The first anion-templated synthesis of a lanthanide-containing interlocked molecule is demonstrated by utilizing a nitrite anion to template initial pseudorotaxane formation. Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane in high yield. Following removal of the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense fluoride selectively.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/anie.201405131
Authors
- Journal:
- Angewandte Chemie (International ed. in English) More from this journal
- Volume:
- 53
- Issue:
- 43
- Pages:
- 11463-11466
- Publication date:
- 2014-10-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:475819
- UUID:
-
uuid:e835a8cd-8962-464b-b598-ff168a866823
- Local pid:
-
pubs:475819
- Source identifiers:
-
475819
- Deposit date:
-
2014-07-23
- ARK identifier:
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- Copyright date:
- 2014
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