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Nitrite-templated synthesis of lanthanide-containing [2]rotaxanes for anion sensing.

Abstract:
The first anion-templated synthesis of a lanthanide-containing interlocked molecule is demonstrated by utilizing a nitrite anion to template initial pseudorotaxane formation. Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane in high yield. Following removal of the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense fluoride selectively.
Publication status:
Published

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Publisher copy:
10.1002/anie.201405131

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
53
Issue:
43
Pages:
11463-11466
Publication date:
2014-10-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:475819
UUID:
uuid:e835a8cd-8962-464b-b598-ff168a866823
Local pid:
pubs:475819
Source identifiers:
475819
Deposit date:
2014-07-23
ARK identifier:

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