Structural, electronic, and magnetic properties of quasi-1D quantum magnets [Ni(HF2)(pyz)2]X (pyz = pyrazine; X = PF6(-), SbF6(-)) exhibiting Ni-FHF-Ni and Ni-pyz-Ni spin interactions.

Manson, JL; Lapidus, SH; Stephens, PW; Peterson, PK; Carreiro, KE; Southerland, HI; Lancaster, T; Blundell, SJ; Steele, AJ; Goddard, PA; Pratt, FL; Singleton, J; Kohama, Y; McDonald, RD; Del Sesto, RE; Smith, NA; Bendix, J; Zvyagin, SA; Kang, J; Lee, C; Whangbo, MH; Zapf, VS; Plonczak, A

Abstract:

[Ni(HF(2))(pyz)(2)]X {pyz = pyrazine; X = PF(6)(-) (1), SbF(6)(-) (2)} were structurally characterized by synchrotron X-ray powder diffraction and found to possess axially compressed NiN(4)F(2) octahedra. At 298 K, 1 is monoclinic (C2/c) with unit cell parameters, a = 9.9481(3), b = 9.9421(3), c = 12.5953(4) Å, and β = 81.610(3)° while 2 is tetragonal (P4/nmm) with a = b = 9.9359(3) and c = 6.4471(2) Å and is isomorphic with the Cu-analogue. Infinite one-dimensional (1D) Ni-FHF-Ni chains prop...

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APA Style

Manson, J. L., Lapidus, S. H., Stephens, P. W., Peterson, P. K., Carreiro, K. E., Southerland, H. I., Lancaster, T., Blundell, S. J., Steele, A. J., Goddard, P. A., Pratt, F. L., Singleton, J., Kohama, Y., McDonald, R. D., Del Sesto, R. E., Smith, N. A., Bendix, J., Zvyagin, S. A., Kang, J., … Plonczak, A. (2011). Structural, electronic, and magnetic properties of quasi-1D quantum magnets [Ni(HF2)(pyz)2]X (pyz = pyrazine; X = PF6(-), SbF6(-)) exhibiting Ni-FHF-Ni and Ni-pyz-Ni spin interactions. Inorganic Chemistry, 50(13), 5990–6009.

MLA Style

Manson, J. L., et al. “Structural, Electronic, and Magnetic Properties of Quasi-1D Quantum Magnets [Ni(HF2)(Pyz)2]X (Pyz = Pyrazine; X = PF6(-), SbF6(-)) Exhibiting Ni-FHF-Ni and Ni-Pyz-Ni Spin Interactions.” Inorganic Chemistry, vol. 50, no. 13, Inorganic chemistry, 2011, pp. 5990–6009.

Chicago Style

Manson, JL, SH Lapidus, PW Stephens, PK Peterson, KE Carreiro, HI Southerland, T Lancaster, et al. 2011. “Structural, Electronic, and Magnetic Properties of Quasi-1D Quantum Magnets [Ni(HF2)(Pyz)2]X (Pyz = Pyrazine; X = PF6(-), SbF6(-)) Exhibiting Ni-FHF-Ni and Ni-Pyz-Ni Spin Interactions.” Inorganic Chemistry 50 (13): 5990–6009.
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