Journal article

Electromeric rhodium radical complexes.

Abstract:: "Chemical Equation Presented" Radical changes: One single P-Rh-P angle determines whether the odd electron in the paramagnetic complex [Rh(trop2PPh)(PPh3)] is delocalized over the whole molecule (see picture, blue) or is localized on the P - Rh unit (red). The two energetically almost degenerate electromers exist in a fast equilibrium, and the "red" complex has the highest spin density at Rh of all low valent Rh complexes observed to date. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA.

Publication status:: Published

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APA Style

Puschmann, F., Harmer, J., Stein, D., Rüegger, H., de Bruin, B., & Grützmacher, H. (2010). Electromeric rhodium radical complexes. Angewandte Chemie (International Ed. in English), 49(2), 385–389.

MLA Style

Puschmann, F., et al. “Electromeric Rhodium Radical Complexes.” Angewandte Chemie (International Ed. in English), vol. 49, no. 2, 2010, pp. 385–89.

Chicago Style

Puschmann, F, J Harmer, D Stein, H Rüegger, B de Bruin, and H Grützmacher. 2010. “Electromeric Rhodium Radical Complexes.” Angewandte Chemie (International Ed. in English) 49 (2): 385–89.
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Publisher copy:: 10.1002/anie.200903201

Authors

+ Puschmann, F More by this author

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+ Harmer, J More by this author

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+ Stein, D More by this author

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+ Rüegger, H More by this author

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+ de Bruin, B More by this author

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Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 49
Issue:: 2
Pages:: 385-389
Publication date:: 2010-01-01
DOI:: 10.1002/anie.200903201
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: radicals

EPR spectroscopy

valence isomerization

redox chemistry

rhodium
Pubs id:: pubs:297497
UUID:: uuid:e765e7db-a93b-4563-8d1a-981864073b83
Local pid:: pubs:297497
Source identifiers:: 297497
Deposit date:: 2012-12-19

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Copyright date:: 2010

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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