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Journal article

Electromeric rhodium radical complexes.

Abstract:
"Chemical Equation Presented" Radical changes: One single P-Rh-P angle determines whether the odd electron in the paramagnetic complex [Rh(trop2PPh)(PPh3)] is delocalized over the whole molecule (see picture, blue) or is localized on the P - Rh unit (red). The two energetically almost degenerate electromers exist in a fast equilibrium, and the "red" complex has the highest spin density at Rh of all low valent Rh complexes observed to date. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200903201

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Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
49
Issue:
2
Pages:
385-389
Publication date:
2010-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Language:
English
Keywords:
Pubs id:
pubs:297497
UUID:
uuid:e765e7db-a93b-4563-8d1a-981864073b83
Local pid:
pubs:297497
Source identifiers:
297497
Deposit date:
2012-12-19

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