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Synthesis and structures of titanium imido complexes of sulfur- and mixed nitrogen-sulfur- and nitrogen-oxygen-donor macrocycles

Abstract:

The first Group 4 complexes of 1,4,7-trithiacyclononane ([9]aneS 3) and the mixed N/S- and N/O-donor macrocycles Me 2[9]aneN 2E (E=S or O) are described. Thus, reaction of the tert-butylimido complex [Ti(N tBu)Cl 2(py) 2] with [9]aneS 3 gives an equilibrium mixture of starting materials and the complex [Ti(N ...

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
INORGANICA CHIMICA ACTA
Volume:
345
Pages:
44-52
Publication date:
2003-03-10
DOI:
ISSN:
0020-1693
URN:
uuid:e4e78b27-10bf-42c2-9022-9392d4c52c30
Source identifiers:
51209
Local pid:
pubs:51209
Language:
English
Keywords:

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