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Analysis of ramped square−wave voltammetry in the frequency domain

Abstract:

We present a new approach to the analysis of square-wave voltammetry in the frequency domain. By extending our earlier work (J. Electroanal. Chem. 480 (2000) 133) on the numerical simulation of ac sine wave voltammetry, we are able to solve the governing equations when a square waveform of any amplitude is superimposed onto a linearly varying dc potential which is swept at a finite scan rate. By considering the numerical results in the frequency domain by using the fast Fourier transform (FFT...

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Authors


DJ Gavaghan More by this author
Journal:
Journal of Electroanalytical Chemistry
Volume:
512
Issue:
1
Pages:
1-15
Publication date:
2001
URN:
uuid:e4afed8b-4c17-4ca1-9bdc-8722b0666bca
Local pid:
cs:4275

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