Journal article
Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4).
- Abstract:
- We report the reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4, [Zn(Im)(2)]). This occurs irrespective of pore occupancy and takes place via a novel high pressure phase (ZIF-4-I) when solvent molecules are present in the pores. A significant reduction in bulk modulus upon framework evacuation is also observed for both ZIF-4 and ZIF-4-I.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/c1cc11985k
Authors
- Journal:
- Chemical Communications More from this journal
- Volume:
- 47
- Issue:
- 28
- Pages:
- 7983-7985
- Publication date:
- 2011-07-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Language:
-
English
- Pubs id:
-
pubs:369791
- UUID:
-
uuid:e40b5079-53ba-4252-9ec9-f88951b0d961
- Local pid:
-
pubs:369791
- Source identifiers:
-
369791
- Deposit date:
-
2013-11-16
- ARK identifier:
Terms of use
- Copyright date:
- 2011
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