Journal article
A short biomimetic synthesis of the meroterpenoids guajadial and psidial A.
- Abstract:
- The biosynthesis of the meroterpenoid guajadial was previously hypothesized to occur via a hetero-Diels-Alder reaction between caryophyllene and an o-quinone methide. This hypothesis has been verified via the biomimetic synthesis of guajadial and psidial A in an aqueous three-component coupling reaction, between caryophyllene, benzaldehyde, and diformylphloroglucinol.
- Publication status:
- Published
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- Publisher copy:
- 10.1021/ol100138k
Authors
- Journal:
- Organic letters More from this journal
- Volume:
- 12
- Issue:
- 8
- Pages:
- 1676-1679
- Publication date:
- 2010-04-01
- DOI:
- EISSN:
-
1523-7052
- ISSN:
-
1523-7060
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:51782
- UUID:
-
uuid:e28e0313-e6d1-483b-9547-d673ea22addc
- Local pid:
-
pubs:51782
- Source identifiers:
-
51782
- Deposit date:
-
2012-12-19
- ARK identifier:
Terms of use
- Copyright date:
- 2010
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