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Journal article

Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine).

Abstract:
CuF(2)(H(2)O)(2)(3-chloropyridine) possesses a five-coordinate Cu(2+) center with a slightly distorted trigonal bypyramidal coordination geometry. Strong intermolecular F···H-O hydrogen bonds enable the formation of 2D layers and provide the primary magnetic exchange path that leads to the stabilization of long-range antiferromagnetic (AFM) order below T(N) = 2.1 K.
Publication status:
Published

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Publisher copy:
10.1039/c2cc37444g

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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics
Role:
Author
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Journal:
Chemical communications (Cambridge, England)
Volume:
49
Issue:
5
Pages:
499-501
Publication date:
2013-01-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:dd73192b-8265-422e-836e-16fffbe0f2cd
Source identifiers:
365451
Local pid:
pubs:365451
Language:
English

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