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Synthesis and ethylene polymerization capability of metallocene-like imido titanium dialkyl compounds and their reactions with (AlBu3)-Bu-i

Abstract:

A series of alkyl- and aryl-imido titanium dialkyl compounds Ti(N'Bu)(Me3[9]aneN3)R2 (R = Me (1), CH 2SiMe3 (3), CH2tBu (4), CH 2Ph (5)), Ti(NR)(Me3[9]aneN3)Me2 (R = iPr (6), Ph. (7), 3,5-C6H3(CF 3)2 (8), 2,6-C6H3iPr 2 (9), 2-C6H4CF3 (10), 2-C 6H4tBu (11)), and Ti(NR)(Me3[9] aneN3)(CH2SiMe3)2 (R = iPr (12), ArF (13)) were prepared and crystallographically characterized in the case of 1, 6-9, and 11 (Me3-[9]aneN3 = 1,4,7-trimethyl triazacyclononane; ArF = C6F 5). These compounds, isolobal with...

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Publication status:
Published

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Publisher copy:
10.1021/om0606136

Authors


Bolton, PD More by this author
Cowley, AR More by this author
Wilson, PJ More by this author
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Journal:
ORGANOMETALLICS
Volume:
25
Issue:
23
Pages:
5549-5565
Publication date:
2006-11-06
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:dd171860-630b-47bd-83d2-4410e5e2c10a
Source identifiers:
51286
Local pid:
pubs:51286
Language:
English

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