Enhanced solar water oxidation and unassisted water splitting using graphite-protected bulk heterojunction organic photoactive layers

Journal article

Polymer donors and non-fullerene acceptors have played an important role as photoactive materials in the development of high-efficiency organic solar cells and have immense potential in devices for direct solar hydrogen generation. However, their use in direct solar water-splitting devices has been limited by their instability in aqueous environment and recombination losses at the interface with catalysts. Here we report anodes containing PM6:D18:L8-BO photoactive layers reaching high solar water oxidation photocurrent density over 25 mA cm −2 at +1.23 V versus reversible hydrogen electrode and days-long operational stability. This was achieved by integrating the organic photoactive layer with a graphite sheet functionalized with earth-abundant NiFeOOH water oxidation catalyst, which provides both water resistance and electrical connection between the catalyst and the photoactive layer without any losses. Using monolithic tandem anodes containing organic PM6:D18:L8-BO and PTQ10:GS-ISO photoactive layers, we achieve a solar-to-hydrogen efficiency of 5%. These results pave the way towards high-efficiency, stable and unassisted solar hydrogen generation by low-cost organic photoactive materials

Authors: Daboczi, M; Eisner, F; Luke, J; Yuan, SW; Lawati, NA

• Publication status: Published
• Peer review status: Peer reviewed
• Publisher: Nature Research
• Journal: Nature Energy
• Volume: 10
• Issue: 5
• Pages: 581-591
• Publication date: 2025-03-18
• DOI: 10.1038/s41560-025-01736-6
• EISSN: 2058-7546
• ISSN: 2058-7546
• Language: English
• Keywords: Chemistry; Optoelectronics; Photocurrent; Organic solar cell; Catalysis; Photoactive layer; Water splitting; Photocatalysis; Energy conversion efficiency; Materials science; Organic chemistry; Chemical engineering; Hydrogen; Composite material; Polymer; Polymer solar cell