Journal article

Anion templated formation of pseudorotaxane and rotaxane monolayers on gold from neutral components.

Abstract:: The surface covalent attachment of indolocarbazole axles enables anion templation to be exploited in the formation of pseudorotaxane assemblies via the threading of neutral isophthalamide macrocycles from solution. The anion selectivity of this templating process can be monitored by a number of surface spectroscopic methods and shows subtle differences compared to the same process in solution. Though the fluxional and disordered nature of ethylene glycol extended axle adlayers prohibits detectable threading on the surface, rotaxane monolayers can be generated by a preassociation of the components and templating anion in solution. The threaded macrocycles therein can subsequently be released and detected by mass spectrometry by reductive stripping of the axle.

Publication status:: Published

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APA Style

Zhao, L., Davis, J., Mullen, K., Chmielewski, M., Jacobs, R., Brown, A., & Beer, P. (2009). Anion templated formation of pseudorotaxane and rotaxane monolayers on gold from neutral components. Langmuir : the ACS Journal of Surfaces and Colloids, 25(5), 2935–2940.

MLA Style

Zhao, L., et al. “Anion Templated Formation of Pseudorotaxane and Rotaxane Monolayers on Gold from Neutral Components.” Langmuir : the ACS Journal of Surfaces and Colloids, vol. 25, no. 5, 2009, pp. 2935–40.

Chicago Style

Zhao, L, J Davis, K Mullen, M Chmielewski, R Jacobs, A Brown, and P Beer. 2009. “Anion Templated Formation of Pseudorotaxane and Rotaxane Monolayers on Gold from Neutral Components.” Langmuir : the ACS Journal of Surfaces and Colloids 25 (5): 2935–40.
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Publisher copy:: 10.1021/la803960z

Authors

+ Zhao, L More by this author

Role:: Author

+ Davis, J More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Mullen, K More by this author

Role:: Author

+ Chmielewski, M More by this author

Role:: Author

+ Jacobs, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

More authors...

Journal:: Langmuir : the ACS journal of surfaces and colloids More from this journal
Volume:: 25
Issue:: 5
Pages:: 2935-2940
Publication date:: 2009-03-01
DOI:: 10.1021/la803960z
EISSN:: 1520-5827
ISSN:: 0743-7463

Language:: English
Pubs id:: pubs:34621
UUID:: uuid:dc0695b8-b327-4c7b-ace8-604851a925a5
Local pid:: pubs:34621
Source identifiers:: 34621
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2009

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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