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Photogenerated reagents for membrane labeling. 2. Phenylcarbene and adamantylidene formed within the lipid bilayer.

Abstract:

Phenylcarbene and adamantylidene have been generated photochemically from the corresponding diazirines within lipid bilayers. Reasonable yields of labeled fatty acid side chains have been observed. The products have been characterized by gas chromatography-mass spectrometry and derive both from the insertion of the carbene into carbon-hydrogen bonds of saturated fatty acids and from the addition of the carbene to the carbon-carbon double bonds of unsaturated fatty acids. In contrast to the r...

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Publication status:
Published

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Publisher copy:
10.1021/bi00605a026

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Journal:
Biochemistry
Volume:
17
Issue:
12
Pages:
2420-2423
Publication date:
1978-06-05
DOI:
EISSN:
1520-4995
ISSN:
0006-2960
URN:
uuid:da614334-cdd4-4ce3-b400-f25865b8a472
Source identifiers:
324325
Local pid:
pubs:324325

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