Journal article
Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling.
- Abstract:
- We report the rapid amorphization of the prototypical substituted zeolitic imidazolate framework, ZIF-8, by ball-milling. The resultant amorphous ZIF-8 (a(m)ZIF-8) possesses a continuous random network (CRN) topology with a higher density and a lower porosity than its crystalline counterpart. A decrease in thermal stability upon amorphization is also evident.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/c2cc33773h
Authors
- Journal:
- Chemical Communications More from this journal
- Volume:
- 48
- Issue:
- 63
- Pages:
- 7805-7807
- Publication date:
- 2012-08-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Language:
-
English
- Pubs id:
-
pubs:341082
- UUID:
-
uuid:d8f42b87-18b2-45fc-a91c-2ab29b6b1836
- Local pid:
-
pubs:341082
- Source identifiers:
-
341082
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 2012
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