- Abstract:
-
The electrochemical oxidation of copper nanoparticles in aqueous solution was studied via their electrolysis upon impacting a carbon electrode held at a suitable anodic potential. The oxidations were found to be quantitative such that complete oxidation of the particle took place allowing their sizing. Experiments were performed in 1.0 M HNO(3) and in 1.0 M HNO(3)-0.1 M KCl. In the former case a two electron oxidation to Cu(2+) was seen at a formal potential of +0.11 V (vs. SCE). In the latte...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/c2cp42585h
-
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- Journal:
- Physical chemistry chemical physics : PCCP
- Volume:
- 14
- Issue:
- 39
- Pages:
- 13612-13617
- Publication date:
- 2012-10-05
- DOI:
- EISSN:
-
1463-9084
- ISSN:
-
1463-9076
- URN:
-
uuid:d8949564-5b0a-466e-b6b1-a024aa563696
- Source identifiers:
-
350488
- Local pid:
- pubs:350488
- Language:
- English
- Copyright date:
- 2012
Journal article
Nanoparticle-electrode impacts: the oxidation of copper nanoparticles has slow kinetics.
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