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Model calculations of magnetic field effects on the recombination reactions of radicals with anisotropic hyperfine interactions

Abstract:

The effects of anisotropic hyperfine interactions on the recombination reactions of spin correlated radical pairs in a weak applied magnetic field are discussed in the context of the radical pair mechanism (RPM). Model calculations are presented for radical pairs containing a single spin-1/2 nucleus with an axial or rhombic coupling to one of the unpaired electrons. The so-called low field effect (LFE) and various resonances in the magnetic field effect (MFE) are calculated. Approximate analy...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
334
Issue:
4-6
Pages:
387-395
Publication date:
2001-02-09
DOI:
ISSN:
0009-2614
URN:
uuid:d79569fc-34f8-47fa-821f-a3f511156d37
Source identifiers:
37727
Local pid:
pubs:37727
Language:
English

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