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(6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]

Abstract:

(6S)-Methyl-L-swainsonine, C 9H 17NO 3, together with the 6R-epimer, was formed in a synthetic sequence in which there was an ambiguity in configuration at position C-6. This ambiguity was resolved by establishing the relative stereochemistry of the title compound by X-ray crystallographic analysis. The absolute configuration was determined by the use of D-glycero-D-gulo-heptono-1,4-lactone as the starting material. © 200...

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Publication status:
Published

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Publisher copy:
10.1107/S1600536806052111

Authors


Hakansson, AE More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Watkin, DJ More by this author
Journal:
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volume:
63
Issue:
1
Pages:
O210-O212
Publication date:
2007-01-05
DOI:
EISSN:
1600-5368
ISSN:
1600-5368
URN:
uuid:d771025e-ecc8-478c-8581-198d6c562cf7
Source identifiers:
40176
Local pid:
pubs:40176
Language:
English

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