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Rock organic carbon oxidation CO2 release offsets silicate weathering sink

Abstract:
Mountain uplift and erosion have regulated the balance of carbon between Earth’s interior and atmosphere, where prior focus has been placed on the role of silicate mineral weathering in CO2 drawdown and its contribution to the stability of Earth’s climate in a habitable state. However, weathering can also release CO2 as rock organic carbon (OCpetro) is oxidized at the near surface; this important geological CO2 flux has remained poorly constrained. We use the trace element rhenium in combination with a spatial extrapolation model to quantify this flux across global river catchments. We find a CO2 release of megatons of carbon annually from weathering of OCpetro in near-surface rocks, rivalling or even exceeding the CO2 drawdown by silicate weathering at the global scale. Hotspots of CO2 release are found in mountain ranges with high uplift rates exposing fine-grained sedimentary rock, such as the eastern Himalayas, the Rocky Mountains and the Andes. Our results demonstrate that OCpetro is far from inert and causes weathering in regions to be net sources or sinks of CO2. This raises questions, not yet fully studied, as to how erosion and weathering drive the long-term carbon cycle and contribute to the fine balance of carbon fluxes between the atmosphere, biosphere and lithosphere.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1038/s41586-023-06581-9

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Earth Sciences
Oxford college:
Wolfson College
Role:
Author
ORCID:
0000-0002-7862-3879
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Institution:
University of Oxford
Division:
MPLS
Department:
Earth Sciences
Oxford college:
St Peter's College
Role:
Author
ORCID:
0000-0002-0499-3332
More by this author
Role:
Author
ORCID:
0000-0002-1770-4333
More by this author
Role:
Author
ORCID:
0000-0003-1135-1765
More by this author
Role:
Author
ORCID:
0000-0003-3162-5129


Publisher:
Springer Nature
Journal:
Nature More from this journal
Volume:
623
Issue:
7986
Pages:
329-333
Place of publication:
England
Publication date:
2023-10-04
Acceptance date:
2023-08-30
DOI:
EISSN:
1476-4687
ISSN:
0028-0836
Pmid:
37794192


Language:
English
Pubs id:
1529219
Local pid:
pubs:1529219
Deposit date:
2023-11-10

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