Journal article

Implications of the solubility of trivalent lanthanides in A Al2 O4 (A=Ca, Sr, and Ba) for their role in phosphors

Abstract:: The technique of standard addition in combination with powder X-ray diffraction was used to identify and quantify the amount of Ln3+ segregating into secondary phases from Ln3+ doped alkaline earth aluminates. Results indicate that Ln3+ ions are more soluble in Ca Al2 O4 than Sr Al2 O4 and Ba Al2 O4, with this being rationalized by the structural details of the A sites. These results indicate that the enhancement of the luminescence afterglow obtained by doping A Al2 O4: Eu2+ samples with Ln3+ ions is a result of much lower doping levels than previously thought. © International Centre for Diffraction Data.

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APA Style

Saines, P., & Kennedy, B. (2006). Implications of the solubility of trivalent lanthanides in A Al2 O4 (A=Ca, Sr, and Ba) for their role in phosphors. Powder Diffraction, 21(4), 285–288.

MLA Style

Saines, P., and B. Kennedy. “Implications of the Solubility of Trivalent Lanthanides in A Al2 O4 (A=Ca, Sr, and Ba) for Their Role in Phosphors.” Powder Diffraction, vol. 21, no. 4, 2006, pp. 285–88.

Chicago Style

Saines, P, and B Kennedy. 2006. “Implications of the Solubility of Trivalent Lanthanides in A Al2 O4 (A=Ca, Sr, and Ba) for Their Role in Phosphors.” Powder Diffraction 21 (4): 285–88.
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Publisher copy:: 10.1154/1.2358362

Authors

+ Saines, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Kennedy, B More by this author

Role:: Author

Journal:: Powder Diffraction More from this journal
Volume:: 21
Issue:: 4
Pages:: 285-288
Publication date:: 2006-01-01
DOI:: 10.1154/1.2358362
EISSN:: 1945-7413
ISSN:: 0885-7156

Language:: English
Keywords:: Standard addition

Lanthanides

Powder X-ray diffraction

Alkaline-earth aluminates

Quantitative analysis
Pubs id:: pubs:286048
UUID:: uuid:d60150c0-9640-4db4-8c6d-145975995b14
Local pid:: pubs:286048
Source identifiers:: 286048
Deposit date:: 2013-11-17

Terms of use

Copyright date:: 2006

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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