Journal article

The effect of the symmetric and asymmetric stretching vibrations of CH4 on the O(3P) + CH4 → OH + CH3 reaction

Abstract:: We present a four-dimensional quantum scattering model to treat reactions of the type CH4 + X → CH3 + XH. The most important feature of the model is that it allows the effect of the symmetric and asymmetric stretching vibrations of CH4 on reactivity to be studied. We used the model to study the CH4 + O(3P) → CH3 + OH reaction. We found that the symmetric stretch vibration is more efficient in promoting reaction than the asymmetric stretch. We also found that exciting any of these stretching m...
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APA Style

Palma, J., & Clary, D. (2000). The effect of the symmetric and asymmetric stretching vibrations of CH4 on the O(3P) + CH4 → OH + CH3 reaction. Physical Chemistry Chemical Physics, 2(18), 4105–4114.

MLA Style

Palma, J., and D. Clary. “The Effect of the Symmetric and Asymmetric Stretching Vibrations of CH4 on the O(3P) + CH4 → OH + CH3 Reaction.” Physical Chemistry Chemical Physics, vol. 2, no. 18, 2000, pp. 4105–14.

Chicago Style

Palma, J, and D Clary. 2000. “The Effect of the Symmetric and Asymmetric Stretching Vibrations of CH4 on the O(3P) + CH4 → OH + CH3 Reaction.” Physical Chemistry Chemical Physics 2 (18): 4105–14.
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Publisher copy:: 10.1039/b003184o

Authors

+ Palma, J More by this author

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Author

+ Clary, D More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Physical & Theoretical Chem

Role:

Author

Bibliographic Details

Journal:: Physical Chemistry Chemical Physics More from this journal
Volume:: 2
Issue:: 18
Pages:: 4105-4114
Publication date:: 2000-09-15
DOI:: 10.1039/b003184o
ISSN:: 1463-9076

Item Description

Language:: English
Pubs id:: pubs:326183
UUID:: uuid:d52f63c0-3fd7-455f-a0b5-ad7e6c3e103e
Local pid:: pubs:326183
Source identifiers:: 326183
Deposit date:: 2013-11-17

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Copyright date:: 2000

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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