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High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2

Abstract:
The electronic structure of the prototypical p-type transparent conducting oxide CuAlO2 has been studied by O K and Cu L3 shell x-ray absorption and emission and Al Kα excited valence photoemission and nonresonant Cu L3 emission spectra are dominated by the Cu 3d partial density of states. All three techniques reveal mixing between O 2p and Cu 3d states. Cu L3 emission spectra excited just above the L3 threshold are dominated by inelastic scattering with 5.5 eV energy loss. This energy is shown to correspond to the separation between the dominant peaks in the filled and empty densities of states.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1103/PhysRevB.72.195115

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
National Centre for Electron Spectroscopy and Surface Analysis, Daresbury Laboratory, Warrington, UK
Role:
Author


Publisher:
American Physical Society
Journal:
Physical Review B More from this journal
Volume:
72
Issue:
19
Pages:
195115
Publication date:
2005-11-01
Edition:
Publisher's version
DOI:
EISSN:
1550-235x
ISSN:
1098-0211


Language:
English
Keywords:
Subjects:
UUID:
uuid:d5227cf2-c5a8-4027-8c5d-423c8e850547
Local pid:
ora:1416
Deposit date:
2008-03-14

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