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α-Substituted vinyl azides: an emerging functionalized alkene

Abstract:

Vinyl azides are highly versatile synthons that provide access to numerous N-heterocycles and other functional groups. α-Substituted vinyl azides (azido vinylidenes) are a special class that display unique reactivity, able to react not only as azides, but also as radical acceptors, enamine-type nucleophiles, and even electrophiles, thus delivering a wide range of nitrogen-containing compounds and their derivatives. An impressive variety of intermediates - such as iminodiazonium ions, nitriliu...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c7cs00017k

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More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Jesus College
Role:
Author
Publisher:
Royal Society of Chemistry
Journal:
Chemical Society Reviews More from this journal
Volume:
46
Issue:
23
Pages:
7208-7228
Publication date:
2017-11-10
Acceptance date:
2017-10-25
DOI:
EISSN:
1460-4744
ISSN:
0306-0012
Pmid:
29125611
Language:
English
Pubs id:
pubs:746098
UUID:
uuid:d449fe32-0b99-4991-9903-53c264a13c7c
Local pid:
pubs:746098
Source identifiers:
746098
Deposit date:
2017-11-20

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