Journal article

Synthesis, characterisation, and magnetic properties of a permethylindenyl manganocene †

Abstract:: The heptamethylindenyl ligand (C9Me7−; Ind*) has been used to synthesise the manganese complex, (η5-Ind*)2Mn, by lithiation of the proligand and subsequent salt metathesis with MnCl2. The solid state molecular structure indicates a low-spin (S = ½) ground state for the Mn2+ metal centre at 100 K. Solution EPR spectroscopy, solid state magnetic susceptibility measurements, and computational studies suggest the complex undergoes a thermally accessible spin-crossover to a high-spin (S = 5/2) state.

Publication status:: Published

Peer review status:: Peer reviewed

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APA Style

Evans, A., Arnold, T. A. Q., Ransom, P., Binding, S. C., Myers, W. K., Crumpton, A. E., Turner, Z. R., Buffet, J., & O'Hare, D. (2025). Synthesis, characterisation, and magnetic properties of a permethylindenyl manganocene †. Dalton Transactions.

MLA Style

Evans, A, et al. “Synthesis, Characterisation, and Magnetic Properties of a Permethylindenyl Manganocene †.” Dalton Transactions, 2025.

Chicago Style

Evans, A, TAQ Arnold, P Ransom, et al. 2025. “Synthesis, Characterisation, and Magnetic Properties of a Permethylindenyl Manganocene †.” Dalton Transactions.
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Files:: Evans_et_al_2025_Synthesis_characterisation_and.pdf

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Publisher copy:: 10.1039/d5dt01345c

Authors

+ Evans, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author
ORCID:: 0000-0003-1681-1628

+ Arnold, TAQ More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author

+ Ransom, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author

+ Binding, SC More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author
ORCID:: 0000-0003-4402-0313

+ Myers, WK More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry
Role:: Author
ORCID:: 0000-0001-5935-9112

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+ University of Oxford More from this funder

Funder identifier:: https://ror.org/052gg0110

Publisher:: Royal Society of Chemistry
Journal:: Dalton Transactions More from this journal
Publication date:: 2025-07-11
Acceptance date:: 2025-07-03
DOI:: 10.1039/d5dt01345c
EISSN:: 1477-9234
ISSN:: 1477-9226

Language:: English
Pubs id:: 2243392
Local pid:: pubs:2243392
Source identifiers:: 3108764
Deposit date:: 2025-07-11
ARK identifier:: ark:/29072/ora_d35920331ba74643a495384843ceec41

Terms of use

Copyright date:: 2025

Licence:: CC Attribution (CC BY) 3.0

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