Journal article
A new monoclinic perovskite allotype in Pr0.6Sr0.4MnO3
- Abstract:
- We report the observation, in Pr0.6Sr0.4MnO3, of a low-temperature phase transition between Pnma and the monoclinic space group I2/a. The I2/a allotype has never previously been observed in the (R1-xAx)MnO3 manganese perovskite system. Furthermore, this space group symmetry is not present in the recently published phase diagram obtained at 30% Mn+4, indicating that electronic doping has a direct effect on the phase stability. The structural and magnetic parameters for the new phase, as obtained from Rietveld refinements of neutron powder diffraction data, are also reported. © 1996 Academic Press.
- Publication status:
- Published
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Authors
- Journal:
- JOURNAL OF SOLID STATE CHEMISTRY More from this journal
- Volume:
- 127
- Issue:
- 2
- Pages:
- 276-282
- Publication date:
- 1996-12-01
- DOI:
- ISSN:
-
0022-4596
- Pubs id:
-
pubs:66394
- UUID:
-
uuid:d249a2e7-5ecf-447b-a525-e21d979295f6
- Local pid:
-
pubs:66394
- Source identifiers:
-
66394
- Deposit date:
-
2012-12-19
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- Copyright date:
- 1996
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