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Pd@Zn core–shell nanoparticles of controllable shell thickness for catalytic methanol production

Abstract:

It is reported that well-dispersed core–shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSe–ZnO precursor in H2 without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 × 10−1 s−1 and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.

Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1039/C6CY01832G

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
Expand authors...
Engineering and Physical Sciences Research Council More from this funder
iChEM consortium More from this funder
Chinese Scholarship Council More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Catalysis Science and Technology Journal website
Volume:
6
Issue:
21
Pages:
7698-7702
Publication date:
2016-09-20
Acceptance date:
2016-09-19
DOI:
EISSN:
2044-4761
ISSN:
2044-4753
Pubs id:
pubs:658925
URN:
uri:cf896b17-9a42-4307-a82c-113eb67f8dc3
UUID:
uuid:cf896b17-9a42-4307-a82c-113eb67f8dc3
Local pid:
pubs:658925
Paper number:
21
Keywords:

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