- Abstract:
-
X-ray crystallographic analysis with Cu Kα radiation established the relative configurations of the stereogenic centers in the title compound, C(15)H(20)N(2)O(5), and clarified mechanistic ambiguities in the synthesis. The conformation of the five-membered ring approximates twisted, about a C-O bond. The absolute configuration of this carbon-branched dipeptide isostere was known based on the use of d-ribose as the starting material. Refinement of the Flack parameter gave an ambiguous result b...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1107/s1600536810039589
-
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- Journal:
- Acta crystallographica. Section E, Structure reports online
- Volume:
- 66
- Issue:
- Pt 11
- Pages:
- o2750-o2751
- Publication date:
- 2010
- DOI:
- EISSN:
-
1600-5368
- ISSN:
-
1600-5368
- URN:
-
uuid:cee27ef5-6690-4a1e-aa9f-c09d4b9be3f7
- Source identifiers:
-
112623
- Local pid:
- pubs:112623
- Language:
- English
- Copyright date:
- 2010
Journal article
(3R,4R,5R)-5-(Acetamido-meth-yl)-N-benzyl-3,4-dihy-droxy-tetra-hydro-furan-3-carboxamide.
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