Journal article
CF2-bridged C60 dimers and their optical transitions
- Abstract:
- Fullerene dyads bridged with perfluorinated linking groups have been synthesized through a modified arc-discharge procedure. The addition of Teflon inside an arc-discharge reactor leads to the formation of dyads, consisting of two C60 fullerenes bridged by -CF2- groups. The bridging groups consisting of electronegative atoms, lead to different energy levels and to new features in the photoluminescence spectrum. A suppression of the singlet oxygen photosensitization, indicated that the radiative decay from singlet to singlet state is favoured against the intersystem crossing singlet to triplet transition.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Preview, Accepted manuscript, pdf, 632.6KB, Terms of use)
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- Publisher copy:
- 10.1002/cphc.201701182
Authors
- Publisher:
- Wiley
- Journal:
- ChemPhysChem More from this journal
- Volume:
- 18
- Issue:
- 24
- Pages:
- 3540-3543
- Publication date:
- 2017-11-16
- Acceptance date:
- 2017-11-02
- DOI:
- EISSN:
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1439-7641
- ISSN:
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1439-4235
- Pmid:
-
29095560
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:743716
- UUID:
-
uuid:cebcad48-7382-4cad-aec2-9d0e559b62ac
- Local pid:
-
pubs:743716
- Source identifiers:
-
743716
- Deposit date:
-
2017-11-20
Terms of use
- Copyright holder:
- Wiley-VCH Verlag GmbH and Co
- Copyright date:
- 2017
- Notes:
- © 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim. This is the author accepted manuscript following peer review version of the article. The final version is available online from Wiley at: 10.1002/cphc.201701182
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