Journal article
In Situ Observation of Topotactic Linker Reorganization in the Aperiodic Metal–Organic Framework TRUMOF‑1
- Abstract:
- We use in situ synchrotron X-ray diffraction measurements to monitor the solvothermal crystallization mechanism of the aperiodic metal–organic framework TRUMOF-1. Following an initial incubation period, TRUMOF-1 forms as a metastable intermediate that subsequently transforms into an ordered product with triclinic crystal symmetry. We determine the structure of this ordered phase, which we call msw-TRUMOF-1, and show that it is related to TRUMOF-1 through topotactic reorganization of linker occupancies. Our results imply that the connectivity of TRUMOF-1 can be reorganized, as required for data storage and manipulation applications.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Publisher copy:
- 10.1021/jacs.4c09487
Authors
+ Engineering and Physical Sciences Research Council
More from this funder
- Funder identifier:
- https://ror.org/0439y7842
- Publisher:
- American Chemical Society
- Journal:
- Journal of the American Chemical Society More from this journal
- Volume:
- 146
- Issue:
- 40
- Pages:
- 27262-27266
- Publication date:
- 2024-09-26
- Acceptance date:
- 2024-09-19
- DOI:
- EISSN:
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1520-5126
- ISSN:
-
0002-7863
- Language:
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English
- Source identifiers:
-
2327409
- Deposit date:
-
2024-10-10
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