Journal article icon

Journal article

Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex

Abstract:

In contrast to [Cp2MoH3](+), which is a thermally stable trihydride complex, the ansa-bridged analogue [(eta-C5H4)(2)-CMe2MoH(H-2)](+) (1) is a thermally labile dihydrogen/hydride complex. Partial deuteration of the hydride ligands allows observation of J(H-D) = 11.9 Hz in 1-d(1) and 9.9 Hz in 1-d(2) (245 K), indicative of a dihydrogen/hydride structure. There is a slight preference for deuterium to concentrate in the dihydrogen ligand. A rapid dynamic process interchanges the hydride and dih...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Publisher copy:
10.1021/ic0496875

Authors


More by this author
Institution:
University of Washington
Department:
Department of Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Jesus College
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
St Catherine's College
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
St Hugh's College
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Expand authors...
Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
43
Issue:
11
Pages:
3475-3482
Publication date:
2004-05-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Language:
English
Keywords:
Subjects:
UUID:
uuid:cdf78fee-df1c-4bf3-99cc-933cc7598c0d
Local pid:
ora:2675
Deposit date:
2009-03-02

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP