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Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex

Abstract:

In contrast to [Cp2MoH3](+), which is a thermally stable trihydride complex, the ansa-bridged analogue [(eta-C5H4)(2)-CMe2MoH(H-2)](+) (1) is a thermally labile dihydrogen/hydride complex. Partial deuteration of the hydride ligands allows observation of J(H-D) = 11.9 Hz in 1-d(1) and 9.9 Hz in 1-d(2) (245 K), indicative of a dihydrogen/hydride structure. There is a slight preference for deuterium to concentrate in the dihydrogen ligand. A rapid dynamic process interchanges the hydride and dih...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/ic0496875

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Institution:
University of Washington
Department:
Department of Chemistry
Role:
Author
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Institution:
University of Oxford
Oxford college:
Jesus College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
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Institution:
University of Oxford
Oxford college:
St Catherine's College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
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Institution:
University of Oxford
Oxford college:
St Hugh's College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
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Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
43
Issue:
11
Pages:
3475-3482
Publication date:
2004-05-03
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:cdf78fee-df1c-4bf3-99cc-933cc7598c0d
Local pid:
ora:2675

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