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Journal article

Metal-organic frameworks as catalyst supports: influence of lattice disorder on metal nanoparticle formation

Abstract:

Because of their high tunability and surface area, metal-organic frameworks (MOFs) show great promise as supports for metal nanoparticles. Depending on the synthesis route, MOFs may contain defects. Here, we show that highly crystalline MIL-100(Fe) and disordered Basolite® F300, with identical iron 1,3,5-benzenetricarboxylate composition, exhibit very divergent properties when used as a support for Pd nanoparticle deposition. While MIL-100(Fe) shows a regular MTN-zeotype crystal structure wit...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's Version

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Publisher copy:
10.1002/chem.201800694

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Role:
Author
ORCID:
0000-0002-7810-637X
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Role:
Author
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Publisher:
Wiley Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
24
Issue:
29
Pages:
7498-7506
Publication date:
2018-04-30
Acceptance date:
2018-03-27
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pubs id:
pubs:846196
URN:
uri:cdbd6703-dc38-4931-a436-04adbd7fd587
UUID:
uuid:cdbd6703-dc38-4931-a436-04adbd7fd587
Local pid:
pubs:846196

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