- Abstract:
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We study the compositional dependence of molecular orientation (multipolar) and orbital (quadrupolar) order in the family of perovskite-like metal–organic frameworks [C(NH2)3]CuxCd1–x(HCOO)3. On increasing the fraction x of Jahn-Teller-active Cu2+, we observe first an orbital disorder/order transition and then a multipolar reorientation transition, each occurring at distinct critical compositions xo = 0.45(5) and xm = 0.55(5). We attribute these transitions to a combination of size, charge di...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted manuscript
- Files:
-
-
(pdf, 1.0MB)
-
- Publisher copy:
- 10.1021/jacs.6b05208
-
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- Grant:
- Grant 279705; Horizon 2020: Marie Sklodowska-Curie no.641887 "DEFNET"
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 138
- Issue:
- 30
- Pages:
- 9393–9396
- Publication date:
- 2016-07-14
- DOI:
- EISSN:
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1520-5126
- ISSN:
-
0002-7863
- URN:
-
uuid:cd462318-6b31-44ba-aac2-790266cc4c77
- Source identifiers:
-
634505
- Local pid:
- pubs:634505
- Paper number:
- 30
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
-
Copyright © 2016 American Chemical Society. This is the accepted manuscript version of the article. The final version is available online from American Chemical Society at: https://doi.org/10.1021/jacs.6b05208
Journal article
Control of multipolar and orbital order in perovskite-like [C(NH2)3]CuxCd1–x(HCOO)3 metal–organic frameworks
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+ European Research Council
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