Journal article
Control of multipolar and orbital order in perovskite-like [C(NH2)3]CuxCd1–x(HCOO)3 metal–organic frameworks
- Abstract:
-
We study the compositional dependence of molecular orientation (multipolar) and orbital (quadrupolar) order in the family of perovskite-like metal–organic frameworks [C(NH2)3]CuxCd1–x(HCOO)3. On increasing the fraction x of Jahn-Teller-active Cu2+, we observe first an orbital disorder/order transition and then a multipolar reorientation transition, each occurring at distinct critical compositions xo = 0.45(5) and xm = 0.55(5). We attribute these transitions to a combination of size, charge di...
Expand abstract
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Accepted manuscript, pdf, 1.0MB)
-
- Publisher copy:
- 10.1021/jacs.6b05208
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Funding
+ European Research Council
More from this funder
Grant:
Horizon 2020: Marie Sklodowska-Curie no.641887 "DEFNET"
Grant 279705
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 138
- Issue:
- 30
- Pages:
- 9393–9396
- Publication date:
- 2016-07-14
- Acceptance date:
- 2016-07-14
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Source identifiers:
-
634505
Item Description
- Pubs id:
-
pubs:634505
- UUID:
-
uuid:cd462318-6b31-44ba-aac2-790266cc4c77
- Local pid:
- pubs:634505
- Deposit date:
- 2016-07-18
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
- Copyright © 2016 American Chemical Society. This is the accepted manuscript version of the article. The final version is available online from American Chemical Society at: https://doi.org/10.1021/jacs.6b05208
If you are the owner of this record, you can report an update to it here: Report update to this record