Journal article icon

Journal article

Control of multipolar and orbital order in perovskite-like [C(NH2)3]CuxCd1–x(HCOO)3 metal–organic frameworks

Abstract:

We study the compositional dependence of molecular orientation (multipolar) and orbital (quadrupolar) order in the family of perovskite-like metal–organic frameworks [C(NH2)3]CuxCd1–x(HCOO)3. On increasing the fraction x of Jahn-Teller-active Cu2+, we observe first an orbital disorder/order transition and then a multipolar reorientation transition, each occurring at distinct critical compositions xo = 0.45(5) and xm = 0.55(5). We attribute these transitions to a combination of size, charge di...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

Actions


Access Document


Files:
Publisher copy:
10.1021/jacs.6b05208

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Expand authors...
More from this funder
Grant:
Grant 279705; Horizon 2020: Marie Sklodowska-Curie no.641887 "DEFNET"
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
138
Issue:
30
Pages:
9393–9396
Publication date:
2016-07-14
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:cd462318-6b31-44ba-aac2-790266cc4c77
Source identifiers:
634505
Local pid:
pubs:634505
Paper number:
30

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP