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A gallium hydride as an oxidizing agent: direct synthesis of IrV complexes via Ga-H bond activation

Abstract:

Reactions of the β-diketiminate-stabilized gallium dihydride (Nacnac)Dipp GaH2 with chelating IrI bis(phosphine) precursors under an H2 atmosphere are shown to provide a simple route to IrV complexes stabilized by strongly σ-donating hydrides and the carbene-like (Nacnac)Dipp Ga donor. Characterization of these systems as seven-coordinate IrV tetrahydride species is supported by single crystal X-ray and neutron diffraction, and by T1 NMR measurements. By contrast related systems featuring mor...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/chem.201704372

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More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Oxford college:
Queens College
Role:
Author
ORCID:
0000-0001-9998-9434
Publisher:
Wiley Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
23
Pages:
16906-16913
Publication date:
2017-11-27
Acceptance date:
2017-10-10
DOI:
EISSN:
1521-3765
Pubs id:
pubs:737309
URN:
uri:cc3dd538-ea14-4954-9f04-a1e0a4a1eb89
UUID:
uuid:cc3dd538-ea14-4954-9f04-a1e0a4a1eb89
Local pid:
pubs:737309

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